Battery knowledge · Recycling and end of life

Flue dust

The fine solids caught from a furnace's off-gas. When a chloride flux is added to a battery smelter, lithium evaporates as lithium chloride and is recovered from the flue dust instead of being lost to the slag.

Example

Recycling and end of life: an example situation

High mass recovery alone does not establish battery-grade purity or refining energy demand.

Read Flue dust alongside Lithium recovery in this context. Getting the lithium back, which smelting loses to slag and older hydrometallurgical flowsheets left until last at low yield. Newer routes take it out first — by roasting or carbonating black mass and washing out a lithium salt — before the other metals are leached.

See it in the plant

How cells are smelted, as a labelled cutaway with numbered steps.
Smelt: how the unit works. Drawn by the Lemonergy recycling study for 100 returned NMC 622 packs of 60 kWh through smelter + hydrometallurgy. The numbers match the steps below. Redraw it for your own fleet in the recycling study ↗
  1. Charge: 30.38 t of cells go in with coke as reductant and silica and lime as flux.
  2. Melt: at 1200–1450 °C carbon and plastics burn and supply heat; the oxides of nickel, cobalt, copper and iron are reduced to metal.
  3. Separate: the heavy alloy collects at the bottom, 8120 kg, and is tapped, granulated and sent to the leach. Aluminium and manganese stay oxides in the slag, 8769 kg.
  4. Volatilise: a chloride flux turns lithium into lithium chloride, which leaves with the gas and is caught as flue dust: 564 kg goes to the lithium step.

Use in Lemonergy

Distinguish recovered material from a qualified product.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Lithium-Ion Battery Recycling

    U.S. Environmental Protection Agency

    Topic background · Battery construction, recycling routes and U.S. waste-management context.

  2. Recycling lithium-ion batteries from electric vehicles

    Gavin Harper et al. · Nature · 2019

    Topic background · Reuse, disassembly and mechanical, hydro-, pyro- and direct recycling routes.