Battery knowledge · Recycling and end of life

Mixer-settler

The working unit of solvent extraction: a chamber where the aqueous solution and the organic extractant are stirred together, and a settler where they separate again by density. Plants run banks of them in series, one bank per metal, with more for stripping the metal back out of the organic.

Example

Recycling and end of life: an example situation

High mass recovery alone does not establish battery-grade purity or refining energy demand.

Read Mixer-settler alongside Pregnant leach solution in this context. The solution that leaves the leach carrying the dissolved metals: lithium, nickel, cobalt and manganese, with copper, iron and aluminium as impurities. It is filtered from the leach residue and purified before the metals are separated.

See it in the plant

How the metals are separated, as a labelled cutaway with numbered steps.
Separate metals: how the unit works. Drawn by the Lemonergy recycling study for 100 returned NMC 622 packs of 60 kWh through mechanical + hydrometallurgy. The numbers match the steps below. Redraw it for your own fleet in the recycling study ↗
  1. Mix and settle: 5544 kg of solution meets an organic extractant in each mixer; in the settler the two liquids separate by density.
  2. Extract in turn: at a controlled pH the first stage loads manganese, the second stage loads cobalt and the third stage loads nickel into the organic; the other metals stay in the water.
  3. Strip and crystallise: sulfuric acid takes each metal back out of the organic, and crystallisers make MnSO₄ 900 kg, CoSO₄ 986 kg, NiSO₄ 2945 kg.
  4. Pass on: lithium stays in the water. 586 kg of raffinate goes to lithium recovery and 127 kg is bled off to stop sodium and sulfate building up.

Use in Lemonergy

Distinguish recovered material from a qualified product.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Lithium-Ion Battery Recycling

    U.S. Environmental Protection Agency

    Topic background · Battery construction, recycling routes and U.S. waste-management context.

  2. Recycling lithium-ion batteries from electric vehicles

    Gavin Harper et al. · Nature · 2019

    Topic background · Reuse, disassembly and mechanical, hydro-, pyro- and direct recycling routes.