Battery knowledge · Recycling and end of life

Relithiation

Restoring the lithium a used cathode material has lost, by heating it with a lithium salt in the solid state or in a hot lithium solution, and re-annealing the crystal. It is the core step of direct recycling and works best on a single, known chemistry. [1]

Also called
cathode regeneration, hydrothermal relithiation

Example

Recycling and end of life: an example situation

High mass recovery alone does not establish battery-grade purity or refining energy demand.

Read Relithiation alongside Cathode active material in this context. The lithium-containing compound in the positive electrode — NMC, NCA, LFP or LCO powder — that supplies the cell’s cyclable lithium. It is the most expensive material in most cells and sets the nominal voltage and much of the energy density.

See it in the plant

How cathode is regenerated directly, as a labelled cutaway with numbered steps.
Regenerate: how the unit works. Drawn by the Lemonergy recycling study for 100 returned NMC 622 packs of 60 kWh through direct regeneration. The numbers match the steps below. Redraw it for your own fleet in the recycling study ↗
  1. Separate: in a flotation cell air bubbles carry the hydrophobic graphite up as froth (6378 kg), while the cathode particles sink.
  2. Wash: the cathode powder is cleaned of electrolyte salts and binder residues.
  3. Relithiate: heated with 27.5 kg of lithium salt, the particles take back the lithium lost in use and their crystal is repaired.
  4. Out: 5180 kg of regenerated cathode, without ever dissolving the metals.

Use in Lemonergy

Distinguish recovered material from a qualified product.

This is a reference concept. No executable Lemonergy block has been verified for this term.

References & further reading

Technical references

  1. Recycling lithium-ion batteries from electric vehicles

    Gavin Harper et al. · Nature · 2019

    Technical reference · Reuse, disassembly and mechanical, hydro-, pyro- and direct recycling routes.

Further reading on this topic

These sources provide broader context; they are not presented as citations for every statement in this entry.

  1. Lithium-Ion Battery Recycling

    U.S. Environmental Protection Agency

    Topic background · Battery construction, recycling routes and U.S. waste-management context.